• 文献标题:   Nickel pyrophosphate combined with graphene nanoribbon used as efficient catalyst for OER
  • 文献类型:   Article
  • 作  者:   SOUZA AS, BEZERRA LS, CARDOSO ESF, FORTUNATO GV, MAIA G
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:  
  • 被引频次:   20
  • DOI:   10.1039/d1ta00817j EA APR 2021
  • 出版年:   2021

▎ 摘  要

Although noble-metal based materials (IrO2 and RuO2) are regarded state-of-the-art catalysts for oxygen evolution reaction (OER), their high price, long-term instability, and scarcity have fueled the search for alternative materials that are relatively cheaper and highly abundant in nature and which can be used for the development of electrolyzers that are suitable for hydrogen production. The present work reports the development and application of a new hybrid catalyst derived from the thermal treatment of a mixture of graphene nanoribbons (GNR) and nickel pyrophosphate (beta-Ni2P2O7); the proposed hybrid material was found to present remarkably improved properties which include easy charge transfer, high electroactive surface area, high activity, and effective resistance to corrosion in OER in alkaline medium. The combination of highly dispersed beta-Ni2P2O7-30 wt% in direct contact with GNR-70 wt%, coupled with the application of thermal treatment - which ensured some enrichment of Ni in the GNiPy350N catalyst, contributed toward the production of an efficient material with excellent and stable OER activity in alkaline conditions. Compared to the state-of-the-art IrO2 (300 mV), the GNiPy350N catalyst required an overpotential of approximately 320 mV to reach the current density of 10 mA cm(-2) when immobilized on carbon paper electrode.