• 文献标题:   Graphene oxide supported N-heterocyclic carbene-palladium as a novel catalyst for the Suzuki-Miyaura reaction
  • 文献类型:   Article
  • 作  者:   SHANG NZ, GAO ST, FENG C, ZHANG HY, WANG C, WANG Z
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Agr Univ Hebei
  • 被引频次:   57
  • DOI:   10.1039/c3ra44620d
  • 出版年:   2013

▎ 摘  要

In this paper, an N-heterocyclic carbene-palladium complex (NHC-Pd2+) was immobilized onto the surface of graphene oxide via a chemical bonding method for the first time. The resultant graphene oxide supported NHC-Pd2+ composite (GO supported NHC-Pd2+) was characterized by transmission electron microscopy, X-ray diffraction spectroscopy, X-ray photoelectron spectroscopy and infrared spectroscopy. It was demonstrated that the GO supported NHC-Pd2+ can act as an efficient catalyst for Suzuki-Miyaura coupling reactions. The yields of the products were in the range of 83% to 96%. The catalyst can be readily recovered and reused for at least 6 consecutive cycles without any significant loss in catalytic activity.