• 文献标题:   A highly efficient MIL-101(Cr)-Graphene-molybdenum oxide nano composite for selective oxidation of hydrogen sulfide into elemental sulfur
  • 文献类型:   Article
  • 作  者:   POURREZA A, ASKARI S, RASHIDI A, FAKHRAIE S, KOOTI M, SHAFIEIALAVIJEH M
  • 作者关键词:   mil101 cr, nanocatalyst, hydrogen sulfide, selective oxidation, porous graphene
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:   RIPI
  • 被引频次:   4
  • DOI:   10.1016/j.jiec.2018.11.040
  • 出版年:   2019

▎ 摘  要

Hybrid composites of MIL-101(Cr) and Nanoporous Graphene with ratios in the range of 10-50% were prepared via hydrothermal synthesis method. This study deals with an experimental investigation on selective oxidation of H2S into elemental sulfur in the range of 200-270 degrees C, the catalyst activity and selectivity toward sulfur was studied. High-temperature reactor tests indicated that the MIL-101(Cr)-NPG50-Mo could be a promising candidate with conversion and selectivity of 100% and 99.5% at 200 degrees C. The MIL-101(Cr)-NPG50-Mo stability showed there were not any significant changes in physical properties, the activity was evaluated after 20 h which was completely stable without any changes. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.