▎ 摘　　要

In this study, a high-performance graphene-based nacre was prepared using gelatin as a bioadhesive with the aid of the bending cycle-induced "mechanical annealed" effect. By this method, this type of graphene-based nacre is endowed with high strength, toughness, and electrical conductive properties, which is very different from other study where only one or two of three properties were improved. The maximum ultimate tensile strength can reach as high as similar to 630.4 MPa when the optimal amount of gelatin was 30 wt%. Meanwhile, it has a high electrical conductivity of similar to 42,624 S/m. Most notably, the periodic bending-induced "mechanical annealing" could further increase the ultimate tensile strength tremendously. After 100 cycles of periodic bending, the ultimate strength reached similar to 902.1 MPa, with a high electrical conductivity of similar to 44,780 S/m. (C) 2015 Elsevier Ltd. All rights reserved.