• 文献标题:   Novel Magnetic Properties of Graphene: Presence of Both Ferromagnetic and Antiferromagnetic Features and Other Aspects
  • 文献类型:   Article
  • 作  者:   MATTE HSSR, SUBRAHMANYAM KS, RAO CNR
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Indian Inst Sci
  • 被引频次:   176
  • DOI:   10.1021/jp903397u
  • 出版年:   2009

▎ 摘  要

Investigations of the magnetic properties of graphenes prepared by different methods reveal that dominant ferromagnetic interactions coexist along with anti ferromagnetic interactions in all of the samples, somewhat like in frustrated or phase-separated systems. All of the graphene samples exhibit room-temperature magnetic hysteresis. The magnetic properties of the graphene samples depend on the number of layers and the sample area, small values of both favoring larger magnetization. Molecular charge-transfer affects the magnetic properties of graphene, interaction with a donor molecule such as tetrathiafulvalene having greater effect than with an electron-withdrawing molecule such as tetracyanoethylene.