• 文献标题:   Gold nanoparticles stabilized by graphene quantum dots as catalysts for C-C bond cleavage in beta-O-4 lignin model compounds
  • 文献类型:   Article
  • 作  者:   ZHANG FW, ZHANG JL, GUO SW
  • 作者关键词:   graphene quantum dot, lignin, gold nanoparticle, cleavage, catalysi
  • 出版物名称:   INORGANIC CHEMISTRY COMMUNICATIONS
  • ISSN:   1387-7003 EI 1879-0259
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   6
  • DOI:   10.1016/j.inoche.2019.03.024
  • 出版年:   2019

▎ 摘  要

In this work, we report oxidative cleavage of C-C bonds in beta-O-4 lignin models that is catalyzed by gold nanoparticles stabilized by graphene quantum dots (AuNPs-GQDs). We demonstrate that GQDs can enhance the catalytic activity of AuNPs. The AuNPs-GQDs shows the highest catalytic activity when the mass ratio of AuNPs to GQDs is of 1:18. Moreover, AuNPs-GQDs exhibits higher activity in the cleavage of C-alpha-C-beta bond of the compounds when their C-beta is adjacent to an oxygen atom. The possible oxidation pathway is proposed.