• 文献标题:   An aqueous hybrid lithium ion capacitor based on activated graphene and modified LiFePO4 with high specific capacitance
  • 文献类型:   Article
  • 作  者:   GAO HF, WANG JF, ZHANG R, WU LF, TAO CA, DENG GJ
  • 作者关键词:   lithium ion capacitor, lithium iron phosphate, graphene, aqueous electrolyte
  • 出版物名称:   MATERIALS RESEARCH EXPRESS
  • ISSN:   2053-1591
  • 通讯作者地址:   Xiangtan Univ
  • 被引频次:   2
  • DOI:   10.1088/2053-1591/aafd57
  • 出版年:   2019

▎ 摘  要

Aqueous Li-ion capacitors (ALICs) have been extensively studied in recent years due to their safety, environmental friendliness and low availability. In this paper, we constructed an ALIC using carbon-coated lithium iron phosphate (LFP) as the positive electrode, activated reduced graphene oxide as the negative electrode and studied its electrochemical performance in 1 M Li2SO4 electrolyte. Here, coating of LFP particles is carried out by dopamine polymerization to form a uniform carbon layer on the surface of the particles, which increases the conductivity and cycle performance of LFP. The optimal ALIC can achieve 82.8 F g(-1) (based on the total mass of the positive and negative materials) at a current density of 0.2 A g(-1), and shows good cycling stability. The specific capacitance can still retain 73% of the initial value after 1000 charge and discharge cycles. The specific energy density can reach 11.5 Wh kg(-1) at a power density of 100 W kg(-1).