• 文献标题:   Graphene anchored with mesoporous NiO nanoplates as anode material for lithium-ion batteries
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   QIU DF, XU ZJ, ZHENG MB, ZHAO B, PAN LJ, PU L, SHI Y
  • 作者关键词:   nio nanoplate, graphene, mesoporou, lithiumion batterie
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Nanjing Univ
  • 被引频次:   41
  • DOI:   10.1007/s10008-011-1466-9
  • 出版年:   2012

▎ 摘  要

Graphene is an excellent substrate to load nanomaterials for energy applications due to its large surface area, excellent conductivity, mechanical strength, and chemical stability. In this study, thermal exfoliated functionalized graphene sheets with good conductivity and high BET surface area are anchored with mesoporous NiO nanoplates by in situ chemical synthesis approach. Electrochemical characterization shows that functionalized graphene sheets-NiO sample exhibits a high capacity of about 700 mAh/g at a discharge current density of 100 mA/g and a good cycling ability. The high capacity and good cycling ability of functionalized graphene sheets -NiO material were attributed to the intimate interaction between the graphene sheets and NiO nanoplates. The graphene sheets not only enhance the conductivity of NiO nanoplates but also improve the structure stability of NiO nanoplates. Furthermore, the mesoporous structure of NiO nanoplates is available to the transfer of electrolyte. Such functionalized graphene sheets-NiO nanocomposite could be a promising candidate material for a high-capacity, low cost, and nontoxic anode for lithium-ion batteries.