• 文献标题:   One-step reducing and dispersing graphene oxide via hydroxypropyl hydrazine and its applications in Cu2+ removal
  • 文献类型:   Article
  • 作  者:   LIU HH, HU XX, GUO HQ, ZHAO JY, LI FR, ZHU DS, LIU SM
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Shandong Univ Technol
  • 被引频次:   3
  • DOI:   10.1039/c9cp01648a
  • 出版年:   2019

▎ 摘  要

Graphene is widely used in numerous scientific fields including physics, chemistry and materials science due to its exceptional electrical, thermal, optical and mechanical properties. However, the poor solubility/dispersibility strongly limits the practical applications of graphene. In this work, hydroxypropyl hydrazine (HPH) was synthesized to reduce graphene oxide (GO) under mild conditions. The as-produced graphene sheets with a 3D-porous structure show admirable dispersion stability in N, N-dimethylacetamide (DMAc) and the graphene sheets are more effective absorbents for Cu2+ removal than those reduced by hydrazine hydrate. A mechanism for removal of epoxides and carboxides from GO by HPH has been proposed. This one-step reducing and dispersing process of GO is more efficient, environmentally benign and safer for the bulk-scale production of 3D porous graphene.