• 文献标题:   Probing the Site-Dependent Kondo Response of Nanostructured Graphene with Organic Molecules
  • 文献类型:   Article
  • 作  者:   GARNICA M, STRADI D, CALLEJA F, BARJA S, DIAZ C, ALCAMI M, ARNAU A, DE PARGA ALV, MARTIN F, MIRANDA R
  • 作者关键词:  
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Univ Autonoma Madrid
  • 被引频次:   13
  • DOI:   10.1021/nl501584v
  • 出版年:   2014

▎ 摘  要

TCNQ molecules are used as a sensitive probe for the Kondo response of the electron gas of a nanostructured graphene grown on Ru(0001) presenting a moire pattern. All adsorbed molecules acquired an extra electron by charge transfer from the substrate, but only those adsorbed in the FCC-Top areas of the moire show magnetic moment and Kondo resonance in the STS spectra. DFT calculations trace back this behavior to the existence of a surface resonance in the low areas of the graphene moire, whose density distribution strongly depends on the stacking sequence of the moire area and effectively quenches the magnetic moment for HCP-Top sites.