▎ 摘　　要

Solar evaporation has become a promising and sustainable technique for harvesting freshwater from seawater and wastewater. However, the applicability and efficacy of solar evaporation need further improvement to achieve high production closer to theoretical limits in compact systems. A 3D (threedimensional) hierarchical inverted conical solar evaporation is developed, which consists of a 3D copper foam skeleton cone decorated with micro-/nanostructures functionalized with graphene oxide, fabricated via easy and scalable wet oxidation, impregnation, and drying at room temperature. The proposed configuration empowers high-efficiency solar absorption, continuous liquid film spreading and transport, enhanced interfacial local evaporation, and rapid vapor diffusion through the pores. More notably, the 3D conical evaporator realizes thermal localization at the skeleton interface and allows evaporation to occur along the complete structure with unimpeded liquid and vapor rapid diffusion. The solar-thermal evaporation efficiency under 1-Sun is as high as 93% with a maximum evaporation rate per unit area of 1.71 kg center dot m(-2)center dot h(-1). This work highlights the benefits of synergistic cooperation of an easily scalable 3D hierarchical functiomicro-/nano-structured copper foam skeletons and functionalized graphene oxide for high-efficient solar evaporation of interest to numerous applications.