• 文献标题:   Synthesis and controlled sulfidation of Ni-Co alloy on reduced graphene oxide as an electrode with enhanced conductivity and capacitance for supercapacitors
  • 文献类型:   Article
  • 作  者:   WU PR, WU CL, CHEN DH
  • 作者关键词:   nico sulfide, nico alloy, reduced graphene oxide, controlled sulfidation, supercapacitor
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Natl Cheng Kung Univ
  • 被引频次:   7
  • DOI:   10.1016/j.jallcom.2017.11.041
  • 出版年:   2018

▎ 摘  要

In this study, the partially sulfidized Ni-Co/reduced graphene oxide (NCS/NC/RGO) hybrid was developed as a supercapacitor electrode material. Because Ni-Co sulfide (NCS) possessed good pseudocapacitor property and non-sulfidized Ni-Co (NC) alloy had high conductivity, we attempted to optimize the electrochemical performance of NCS/NC/RGO hybrid by controlling the sulfidation of NC/RGO hybrid. RGO was incorporated as a substrate to help the dispersion of NCS/NC nanoparticles and contribute some capacitance. It was demonstrated that an appropriate sulfidation of NC/RGO hybrid could lead to the highest capacitance effectively. Moreover, the optimal NCS/NC/RGO hybrid also exhibited good stability. The result revealed that the strategy to optimize the capacitor performance of NCS/NC/RGO hybrid via the controlled sulfidation of NC/RGO hybrid was indeed effective. (C) 2017 Elsevier B.V. All rights reserved.