• 文献标题:   Gram-Scale Production of Graphene Powder via a Quasi-physical Process and Its Application in Electrode Material for Lithium-Ion Battery
  • 文献类型:   Article
  • 作  者:   ZHANG Y, ZHU X, XU MW, ZHOU C, SONG XP, YANG S
  • 作者关键词:   anode material, conducting additive, exfoliation, graphene, lithiumion battery
  • 出版物名称:   ADVANCED ENGINEERING MATERIALS
  • ISSN:   1438-1656 EI 1527-2648
  • 通讯作者地址:   Xi An Jiao Tong Univ
  • 被引频次:   0
  • DOI:   10.1002/adem.201800891
  • 出版年:   2019

▎ 摘  要

Graphene powder is an attractive conducting additive for the electrodes of lithium-ion battery (LIB). However, the practical application of graphene is hampered by the lack of reliable methods for its production. Here, the authors report a promising method for the synthesis of graphene powder, which exhibits the functionalities both in gram-scale production and high-quality products. As a validation, the authors show that the introduced graphene matrix can greatly improve the electrochemical activity and cycle stability of the Co3O4 nanoparticles. Typically, when 40 wt% of graphene is introduced, the obtained Co3O4/graphene nanocomposite can stably cycle up to more than 50 cycles with a reversible capacity above 530 mAh g(-1). Simultaneously, a limited initial irreversible capacity less than 40 mAh g(-1) is also achieved. The attainment of such properties in Co3O4/graphene nanocomposite offers the prospects for the practical applications of graphene in industry for better LIBs.