• 文献标题:   Tuning the Mechanical and Adsorption Properties of Silica with Graphene Oxide
  • 文献类型:   Article
  • 作  者:   SINGH VK, CURA ME, LIU XW, JOHANSSON LS, GE YL, HANNULA SP
  • 作者关键词:   ceramic, copper removal, graphene oxide, mechanical propertie, optical propertie
  • 出版物名称:   CHEMPLUSCHEM
  • ISSN:   2192-6506
  • 通讯作者地址:   Aalto Univ
  • 被引频次:   7
  • DOI:   10.1002/cplu.201402138
  • 出版年:   2014

▎ 摘  要

Silica and graphene oxide (GO) were synthesized by modified Stober and Hummer's methods, respectively. Silica/GO composite powders of different compositions were obtained by introduction of GO sheets in between silica particles through a hydrothermal synthesis. Composites were characterized by Fourier transform infrared spectroscopy, X-ray diffraction analysis, and scanning and transmission electron microscopy. Density measurements were performed with a pycnometer and chemical analyses of powders were performed by energy-dispersive X-ray and X-ray photoelectron spectroscopies. Composite powders showed an improvement in the Cu2+ ion adsorption property relative to pure silica. Composite powders were further consolidated at 1200 degrees C under 50MPa pressure in vacuum by pulsed electric current sintering. Transparency in the UV/Vis region, the electrical conductivity, and the toughness of consolidated samples were altered by varying the GO content in the starting materials. Studies suggest that the use of GO as a reinforcing agent not only improves the mechanical properties of transparent silica ceramic, but also improves the electrical conductivity and adsorption properties of silica.