• 文献标题:   Bismuth vanadate/graphene quantum dot: A new nanocomposite for photoelectrochemical determination of dopamine
  • 文献类型:   Article
  • 作  者:   PRADO TM, CARRICO A, CINCOTTO FH, FATIBELLO O, MORAES FC
  • 作者关键词:   bismuth vanadate, reduced graphene oxide, dopamine, visible light, photoelectrochemistry
  • 出版物名称:   SENSORS ACTUATORS BCHEMICAL
  • ISSN:  
  • 通讯作者地址:   Univ Fed Sao Carlos
  • 被引频次:   15
  • DOI:   10.1016/j.snb.2019.01.059
  • 出版年:   2019

▎ 摘  要

A photoelectrochemical sensor for dopamine was fabricated by the immobilization of bismuth vanadate (BiVO4) and graphene quantum dots on a fluorine-doped tin oxide (FTO) glass electrode. Electrochemical impedance spectroscopy experiments demonstrated that the presence of graphene quantum dots contributed to the decrease in charge transfer resistance of the sensor under irradiation of visible light in the presence of dopamine. The photocurrent signals obtained were proportional to the dopamine concentration from 3.6 x 10(-8) to 2.5 x 10(-4) mol L-1, with a detection limit estimated at 8.2 x 10(-9) mol L-1 and a limit of quantification at 2.7 x 10(-8) mol L-1.