• 文献标题:   Graphene supercapacitor with both high power and energy density
  • 文献类型:   Article
  • 作  者:   YANG H, KANNAPPAN S, PANDIAN AS, JANG JH, LEE YS, LU W
  • 作者关键词:   graphene, supercapacitor, energy storage, nanoporous material
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Ohio State Univ
  • 被引频次:   42
  • DOI:   10.1088/1361-6528/aa8948
  • 出版年:   2017

▎ 摘  要

Supercapacitors, based on fast ion transportation, are specialized to provide high power, long stability, and efficient energy storage using highly porous electrode materials. However, their low energy density excludes them from many potential applications that require both high energy density and high power density performances. Using a scalable nanoporous graphene synthesis method involving an annealing process in hydrogen, here we show supercapacitors with highly porous graphene electrodes capable of achieving not only a high power density of 41 kW kg(-1) and a Coulombic efficiency of 97.5%, but also a high energy density of 148.75 Wh kg(-1). A high specific gravimetric and volumetric capacitance (306.03 F g(-1) and 64.27 F cm(-3)) are demonstrated. The devices can retain almost 100% capacitance after 7000 charging/discharging cycles at a current density of 8 A g(-1). The superior performance of supercapacitors is attributed to their ideal pore size, pore uniformity, and good ion accessibility of the synthesized graphene.