• 文献标题:   Electrochemical synthesis of nanosized hydroxyapatite/graphene composite powder
  • 文献类型:   Article
  • 作  者:   MISKOVICSTANKOVIC V, ERAKOVIC S, JANKOVIC A, VUKASINOVICSEKULIC M, MITRIC M, JUNG YC, PARK SJ, RHEE KY
  • 作者关键词:   graphene, hydroxyapatite, electrochemical synthesi, composite, antibacterial activity
  • 出版物名称:   CARBON LETTERS
  • ISSN:   1976-4251 EI 2233-4998
  • 通讯作者地址:   Kyung Hee Univ
  • 被引频次:   4
  • DOI:   10.5714/CL.2015.16.4.233
  • 出版年:   2015

▎ 摘  要

Electrochemical synthesis was employed to prepare a novel hydroxyapatite/graphene (HAP/Gr) composite powder suitable for medical applications as a hard tissue implant (scaffold). The synthesis was performed in a homogeneous dispersion containing Na(2)H(2)EDTA center dot 2H(2)O, NaH2PO4 and CaCl2 with a Ca/EDTA/PO43- concentration ratio of 0.25/0.25/0.15M, along with 0.01 wt% added graphene nanosheets, at a current density of 137 mA cm(-2) and pH value of 9.0. The field emission scanning electron microscopy and transmission electron microscopy observations of the composite HAP/Gr powder indicated that nanosized hydroxyapatite particles were uniformly placed in the graphene overlay. Raman spectroscopy, Fourier transform infrared spectroscopy and X-ray diffraction confirmed graphene incorporation in the HAP/Gr powder. The electrochemically prepared HAP/Gr composite powder exhibited slight antibacterial effect against the growth of the bacterial strain Staphylococcus aureus.