• 文献标题:   Lead Oxide Microparticles Coated by Ethylenediamine-Cross-Linked Graphene Oxide for Lithium Ion Battery Anodes
  • 文献类型:   Article
  • 作  者:   GUO A, CHEN E, WYGANT BR, HELLER A, MULLINS CB
  • 作者关键词:   lithiumion batterie, lead oxide, microparticle, graphene oxide, carbon coating
  • 出版物名称:   ACS APPLIED ENERGY MATERIALS
  • ISSN:   2574-0962
  • 通讯作者地址:   Univ Texas Austin
  • 被引频次:   9
  • DOI:   10.1021/acsaem.9b00401
  • 出版年:   2019

▎ 摘  要

Lead-based anodes in Li-ion batteries have potential in stationary storage applications, due to their high theoretical volumetric energy density. In this study, the cycle performance of PbO was improved by coating it with a network of graphene oxide sheets, cross-linked by ethylenediamine. The carbon coating reduced electrode capacity degradation from 0.42% to 0.22% per cycle over 200 cycles, increased Coulombic efficiency from 96% to 99%, and increased the accessible capacity of the electrodes through improved electrical connectivity. This low-temperature carbon coating technique is potentially advantageous to other metastable and low-melting electroactive materials.