• 文献标题:   Covalent organic frameworks (COFs)-derived nitrogen-doped carbon/reduced graphene oxide nanocomposite as electrodes materials for supercapacitors
  • 文献类型:   Article
  • 作  者:   IBRAHIM M, ABDELHAMID HN, ABUELFTOOH AM, MOHAMED SG, WEN Z, SUN XH
  • 作者关键词:   ndoped carbon, covalent organic framework, supercapacitor, carbon nanomaterial
  • 出版物名称:   JOURNAL OF ENERGY STORAGE
  • ISSN:   2352-152X EI 2352-1538
  • 通讯作者地址:  
  • 被引频次:   16
  • DOI:   10.1016/j.est.2022.105375 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

This study reports the ex-situ and in-situ (one-pot) synthesis of a triazine covalent organic framework (COF)/graphene oxide (GO) nanocomposite. The materials are used to synthesize N-doped carbon (N-doped C)/reduced GO (rGO) via a simple carbonization step. The nanocomposites are used as electrode materials for supercapacitors. N-doped C/rGO synthesized via the in-situ method exhibits good electrochemical performance compared to the materials synthesized via the ex-situ procedure. N-doped C/rGO_In-situ offers a specific capacitance of 234 Fmiddotg(-1) at the current density of 0.8 Amiddotg(-1). Two symmetric supercapacitor devices illuminate a white light-emitting diode (LED) lamp. A device using an N-doped C/rGO_In situ electrode shows high specific energy of 14.6 Wmiddothmiddotkg(-1) and high specific power of 400 Wmiddotkg(-1), with only a 14 % decrease in the capacitance performance after 3500 cycles. The simple synthesis procedure using the in-situ method and the high electrochemical performance of the synthesized materials may advance the exploration of an effective electrode material for supercapacitors.