• 文献标题:   Synthesis of novel and room temperature-operable palladium complexes on graphene oxide: An efficient recyclable catalyst for Suzuki-Miyaura coupling reactions
  • 文献类型:   Article
  • 作  者:   QIAN Y, SO J, LEE MY, HWANG S, JIN MJ, SHIM SE
  • 作者关键词:   graphene oxide, conjugated ligand, palladium, heterogeneous catalyst, suzukimiyaura coupling
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:   Inha Univ
  • 被引频次:   4
  • DOI:   10.1016/j.jiec.2019.03.033
  • 出版年:   2019

▎ 摘  要

Novel palladium complexes composed of palladium and a conjugated ligand (imine-aldehyde) were immobilized on graphene oxide. The developed catalyst was characterized by XPS, and TEM. The novel catalyst was proven to be highly efficient for the Suzuki-Miyaura coupling reaction of aryl halides (Br, Cl) with arylboronic acids under mild conditions with a low amount of catalyst (0.1 mol%). In particular, excellent yields could be also obtained at room temperature within 1 h for monosubstituted aryl bromide coupling. Furthermore, the novel catalyst could be reused at least ten times without significant loss of its catalytic activities. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.