• 文献标题:   An overview of the electrochemical performance of modified graphene used as an electrocatalyst and as a catalyst support in fuel cells
  • 文献类型:   Review
  • 作  者:   SOO LT, LOH KS, MOHAMAD AB, DAUD WRW, WONG WY
  • 作者关键词:   graphene, reduced graphene oxide, modified graphene, functionalization, electrochemical performance
  • 出版物名称:   APPLIED CATALYSIS AGENERAL
  • ISSN:   0926-860X EI 1873-3875
  • 通讯作者地址:   Univ Kebangsaan Malaysia
  • 被引频次:   50
  • DOI:   10.1016/j.apcata.2015.03.008
  • 出版年:   2015

▎ 摘  要

Fuel cells have recent drawn particular attention from scientists because they are both environmental friendly and highly efficient energy devices. Nevertheless, the commercialization of fuel cells is restricted by the high cost of Pt and the low stability of carbon supports, which are susceptible to corrosion. Graphene is a carbon support that may be able to replace carbon black because it offers a larger active surface area and better resistance toward corrosion. In this paper, graphene-supported Pt-based materials and non-Pt metals are compared to the analogous systems supported on carbon black. The primary issues attributed to graphene are its poor dispersion in solvent and electrochemical inertness. These issues can be resolved by modifying the structure of graphene, obtaining the desired chemical and physical properties through heteroatom doping or chemical functionalization. The properties of the modified graphene include improved solubility in solvent, which is attributed to the presence of foreign atoms or molecules on the graphene sheet; this change leads to a modification of its hydrophilicity. The effects of these additional functional groups or substituted elements on the electrochemical performance of the graphene catalysts in a fuel cell system are discussed herein. In the later sections of this paper, the applications of modified graphene as a catalyst support and as an electrocatalyst for fuel cells are reviewed. (C) 2015 Elsevier B.V. All rights reserved.