• 文献标题:   Highly microporous-graphene aerogel monolith of unidirectional honeycomb macro-textures
  • 文献类型:   Article
  • 作  者:   WANG SW, WANG Z, FUTAMURA R, ENDO MR, KANEKO K
  • 作者关键词:   graphene monolith, hierarchical porosity, free drying, unidirectional structure
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   Shinshu Univ
  • 被引频次:   4
  • DOI:   10.1016/j.cplett.2017.02.007
  • 出版年:   2017

▎ 摘  要

The highly microporous graphene aerogel monolith of unidirectional textures is obtained from reduction and KOH activation of colloidal graphene oxide prepared with an ice-templating route. The free-standing geometry and well-aligned textures of graphene monolith are persevered even after an intensive KOH activation at 973 K, although the frame structure is slightly disordered. The non-overestimated surface area of the KOH activated graphene monolith is 990 m(2) g(-1). The free-standing graphene aerogel monolith has predominant microporosity with appropriate macroporosity and a low bulk density of 8 +/- 0.5 mg cm(-3), being one of the lightest materials of the reported porous graphene materials. (C) 2017 Elsevier B.V. All rights reserved.