• 文献标题:   Preparation and characterization of silk sericin/glycerol/graphene oxide nanocomposite film
  • 文献类型:   Article
  • 作  者:   YUN H, KIM MK, KWAK HW, LEE JY, KIM MH, KIM EH, LEE KH
  • 作者关键词:   silk sericin, graphene oxide, nanocomposite, plasticizer, biocompostable material
  • 出版物名称:   FIBERS POLYMERS
  • ISSN:   1229-9197 EI 1875-0052
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   18
  • DOI:   10.1007/s12221-013-2111-2
  • 出版年:   2013

▎ 摘  要

Sericin (SS) is a protein that is secreted by silkworms, but it is usually discarded during the degumming process. To obtain and make use of the sericin, we prepared sericin/glycerol/graphene oxide nanocomposite film. The inherent brittleness of pure sericin film was improved by the addition of glycerol (Glc) as a plasticizer. To compensate for the reduced stiffness, we added graphene oxide (GO) into the SS/Glc film. At concentrations of up to 0.8 wt% relative to SS, GO dispersed evenly in the SS matrix without any agglomeration. The maximum tensile strength (9.5 +/- 0.7 MPa) and Young's modulus (414.4 +/- 23.2 MPa) were obtained when the GO content was 0.8 wt% relative to SS. The elongation of SS/Glc/GO nanocomposite film also increased by approximately 40 % compared to SS/Glc film. The strong interfacial interaction between the SS and the GO was responsible for the increased stiffness. The increased elongation was due to the reduced crystallinity of the sericin matrix in the presence of GO.