• 文献标题:   Enhanced cycle stability of iron(II, III) oxide nanoparticles encapsulated with nitrogen-doped carbon and graphene frameworks for lithium battery anodes
  • 文献类型:   Article
  • 作  者:   PHAMCONG D, KIM SJ, JEONG SY, KIM JP, KIM HG, BRAUN PV, CHO CR
  • 作者关键词:   nitrogendoped carbon, graphene oxide, iron oxide, nanoparticle, cycle stability
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Pusan Natl Univ
  • 被引频次:   8
  • DOI:   10.1016/j.carbon.2017.12.073
  • 出版年:   2018

▎ 摘  要

Nitrogen-doped carbon-coated and graphene oxide-wrapped Fe3O4 nanoparticles were prepared using the electrostatic force between polyethyleneimine-functionalized Fe3O4 nanoparticles and graphene oxide layers, followed by annealing in an N-2 atmosphere (Fe3O4@NCG). The electrochemical performance of Fe3O4@NCG was superior to that of graphene oxide-or reduced graphene oxide-wrapped Fe3O4 nanoparticles and carbon-coated Fe3O4 nanoparticles. Fe3O4@NCG exhibited stable specific capacity of similar to 895 mAh g(-1) after 350 cycles over the voltage range 0.001-3.0 V vs. Li/Li+. The superior performance of Fe3O4@NCG was attributed to the presence of a nitrogen-doped carbon layer and networks of reduced graphene oxide. The chemical route-derived Fe3O4@NCG may be a promising anode material for high-performance lithium-ion batteries. (C) 2017 Elsevier Ltd. All rights reserved.