• 文献标题:   Cabbage-like nitrogen-doped graphene/sulfur composite for lithium-sulfur batteries with enhanced rate performance
  • 文献类型:   Article
  • 作  者:   CUI ZQ, MEI T, YAO J, HOU BF, ZHU X, LIU XH, WANG XB
  • 作者关键词:   cabbagelike structure, folds gullie, nitrogendoped graphene, high rate, lithiumsulfur batterie
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Hubei Univ
  • 被引频次:   8
  • DOI:   10.1016/j.jallcom.2018.04.234
  • 出版年:   2018

▎ 摘  要

The cabbage-like nitrogen-doped graphene/sulfur composite (NG/S) was prepared in this work. This novel cabbage-like morphology has a three-dimensional connected structure with unique tiny ravines and thin folds, which can offset the defect of nonconductive sulfur species and store sulfur. Based on the new structure, the sulfur loading of NG/S is up to 74 wt% by thermogravimetric analysis. Electrochemistry tests indicate that the NG/S cathode delivers a discharge specific capacity of 1309 mAh g(-1) at 1 C (1 C = 1672 mAg(-1)), and the stable reversible capacity can be maintained at approximately 663 mAh g(-1) after 300 cycles at 1 C, together with the capacity decay of per cycle is only 0.02%. (C) 2018 Elsevier B.V. All rights reserved.