• 文献标题:   Nitrogen-Doped Few-Layer Graphene Grown Vertically on a Cu Substrate via C-60/Nitrogen Microwave Plasma and Its Field Emission Properties
  • 文献类型:   Article
  • 作  者:   ZHENG H, CHU QQ, ZHENG P, ZHENG L, ZHENG XL, SHAO LH, WU FM, WU ZT, JIANG Y, ZHANG Y
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Hangzhou Dianzi Univ
  • 被引频次:   0
  • DOI:   10.1021/acs.jpcc.0c05563
  • 出版年:   2020

▎ 摘  要

Vertical few-layer graphene (V-FLG) sheet is expected to be a high field emitter due to its electrical properties and open surface with sharp edges. However, the complicated and tedious preparation method using gaseous carbon-containing precursor limited the universal application of V-FLG. This paper reports a novel, simple, and green method to prepare vertical nitrogen-doped few-layer graphene (V-NFLG) on the metal surfaces that exhibit excellent field emission properties. The V-NFLG was grown on a Cu substrate using C-60 as a precursor with the help of a nitrogen microwave plasma. Growth and doping mechanisms for the few-layer graphene are suggested based on microwave plasma emission spectra of C-60/nitrogen. The as-prepared NFLG exhibits remarkable field emission performance, with a high field enhancement factor (7430 at the high field), a low turn-on field (1.45 V/mu m at 10 mu A/cm(2)), and high stability (within +/- 4%), showing its great potential for field emission applications.