• 文献标题:   High-rate Li4Ti5O12/porous activated graphene nanoplatelets composites using LiOH both as lithium source and activating agent
  • 文献类型:   Article
  • 作  者:   WANG DD, SHAN ZQ, LIU XY, NA R, WANG J, LIU HT, TIAN JH
  • 作者关键词:   lowcost green, hydrothermal activation, lioh solution, li4ti5o12 nanoparticle, lithiumion batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   10
  • DOI:   10.1016/j.electacta.2017.12.185
  • 出版年:   2018

▎ 摘  要

The Li4Ti5O12/activated graphene nanoplatelets ( Li4Ti5O12/a-GNPs) composites are prepared via a low-cost, green, one-pot hydrothermal process by using LiOH both as lithium source and activating agent for the first time. The LiOH solution concentration and hydrothermal time are optimized to obtain the pure Li4Ti5O12/a-GNPs. The synergistic effects of the nanosized Li4Ti5O12 and the three-dimensional porous a-GNPs endow the composites with convenient lithium ion diffusion channels and efficiently conductive structures for electron and ion transport. As anticipated, the Li4Ti5O12/a-GNPs deliver an outstanding rate capability of 125 and 113mA h g(-1) at 80 and 100 C, respectively, and an excellent cycling stability with 90.21% capacity retention after 2000 cycles at 10 C. These results are much better than those of the Li4Ti5O12/GNPs and pure Li4Ti5O12, demonstrating Li4Ti5O12/a-GNPs are promising anode materials for lithium-ion batteries of high current density applications. (C) 2017 Elsevier Ltd. All rights reserved.