• 文献标题:   High-Performance Hydrazine Sensor Based on Graphene Nano Platelets Supported Metal Nanoparticles
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   LIU Y, QIU ZP, WAN QJ, WANG ZH, WU KB, YANG NJ
  • 作者关键词:   hydrazine, aupd nanoparticle, graphene, electrodeposition
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Wuhan Inst Technol
  • 被引频次:   7
  • DOI:   10.1002/elan.201500531
  • 出版年:   2016

▎ 摘  要

Surface coating of graphene nano platelets with gold-palladium nanoparticles (AuPd NPs) was conducted via potentiostatic electrodeposition from a mixture of HAuCl4 and H2PdCl4. AuPd NPs were characterized using SEM, TEM, XRD and energy dispersive X-ray spectroscopy. The AuPd NPs with the diameter of about 30-60nm were alloyed and well-dispersed on the graphene surface. Electrochemistry of hydrazine on AuPd NPs was investigated using cyclic voltammetry and chronoamperometry, indicating high electrocatalytic ability of AuPd NPs towards oxidation of hydrazine. Under the optimized conditions, the oxidation current was linear to the hydrazine concentration in the range of 0.02-166.6 mu M. The calculated detection limit was 5nM (S/N=3).