• 文献标题:   Scalable synthesis and electrochemical performance of mesoporous graphene from calcium carbonate by magnesiothermic reaction
  • 文献类型:   Article
  • 作  者:   HAN TL, SUN BS, LI QK, WANG CD
  • 作者关键词:   mesoporous graphene, scalable synthesi, magnesiothermic reaction, calcium carbonate, electrochemical performance
  • 出版物名称:   PROGRESS IN NATURAL SCIENCEMATERIALS INTERNATIONAL
  • ISSN:   1002-0071 EI 1745-5391
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.pnsc.2022.05.003
  • 出版年:   2022

▎ 摘  要

A novel scalable synthetic method of mesoporous graphene has been developed using the compressed mixture of Mg and excess CaCO3 in a closed container. The generated solid oxide and unreacted CaCO3 could act as mesopore-forming agents, and the closed container could prevent the carbon dioxide from CaCO3 flow away. As a result, the graphenes with a large number of 2-30 nm mesopores and high utilization ratio of Mg achieved. The graphenes had high specific surface area and excellent electrochemical performance. In particular, the Mg utilization ratio was up to 53.3% in the preparation of graphene using 2:1 CaCO3/Mg at 700 degrees C, which is superior to previous researches. The obtained mesoporous graphene exhibited high specific surface area of 743.7 m(2)g(-1), large specific capacitance of 140 F g(-1), and high capacitance retention rate of 64.3%.