▎ 摘 要
A novel scalable synthetic method of mesoporous graphene has been developed using the compressed mixture of Mg and excess CaCO3 in a closed container. The generated solid oxide and unreacted CaCO3 could act as mesopore-forming agents, and the closed container could prevent the carbon dioxide from CaCO3 flow away. As a result, the graphenes with a large number of 2-30 nm mesopores and high utilization ratio of Mg achieved. The graphenes had high specific surface area and excellent electrochemical performance. In particular, the Mg utilization ratio was up to 53.3% in the preparation of graphene using 2:1 CaCO3/Mg at 700 degrees C, which is superior to previous researches. The obtained mesoporous graphene exhibited high specific surface area of 743.7 m(2)g(-1), large specific capacitance of 140 F g(-1), and high capacitance retention rate of 64.3%.