▎ 摘 要
Background: A bimetal (Fe/Ni) doped cobalt-nitrogen-carbon matrix (Fe/Ni-CoNC) with hierarchical architecture originating from zeolitic imidazolate framework (ZIF-67) is purposely designed. Methods: The metals within the Co-N-C matrix are well distributed. Besides, Fe/Ni-CoNC was supported on reduced graphene oxide (RGO). We demonstrate that the three-element combination can synergistically contribute to different advantages for microwave absorption. Therefore, the combination of Fe and Ni synergized the absorber to obtain a good impedance match for the best microwave absorption. Significant Findings: The synthesized Fe/Ni-CoNC/RGO with optimized element components exhibited an excellent wave absorption of -51.6 dB at 7.2 GHz obtained with a thin thickness of 2.5 mm. When combining Fe/Ni-CoNC/RGO with a thermoset resin, namely polydicyclopentadiene (PDCPD), the final product reached a maximum absorption of -24.5 dB with a thickness of 1.5 mm. This compounding confirmed that interfacial polarization, defect polarization, and natural resonance are synchronously enhanced for improved absorption performance. (c) 2022 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.