• 文献标题:   Aqueous suspension of biocompatible reduced graphene oxide- Au NPs composite as an effective recyclable catalyst in a Betti reaction
  • 文献类型:   Article
  • 作  者:   FATHALIPOUR S, ATAEI B, JANATI F
  • 作者关键词:   modified graphene oxide, au nanoparticle, polyethylene glycol, betti reaction
  • 出版物名称:   MATERIALS SCIENCE ENGINEERING CMATERIALS FOR BIOLOGICAL APPLICATIONS
  • ISSN:   0928-4931 EI 1873-0191
  • 通讯作者地址:   Payame Noor Univ
  • 被引频次:   8
  • DOI:   10.1016/j.msec.2018.12.048
  • 出版年:   2019

▎ 摘  要

Synthesis of noble metal nanoparticles (NPs) on modified graphene oxide with biocompatible polymers has attracted significant due to their unique properties and various applications. In this research, covalent-modified graphene oxide (MGO) with diacid terminated poly (ethylene glycol) (PEG) was used as a substrate and stabilizing of Au (III). The reduction of MGO-Au (III) complex with hydrazine monohydrate under reflux condition obtained biocompatible reduced MGO (rMGO)-Au NPs. Diacid terminated PEG obtained from the reaction of PEG with succinic anhydride in the presence of N,N- dicyclohexylcarbodiimide (DCC) and 4-methylamino pyridine (DMAP) was attached to GO sheets to prevent from the aggregation of rMGO sheets and Au NPs. The resulting aqueous suspension was characterized through UV vis, FT-IR, Raman, XRD, DLS-zeta potential, SEM, EDX and TEM. Furthermore, nanocomposite showed good catalytic behavior in Betti reaction- synthesis of 1-(alpha-aminoalkyl)-2-naphthols. The favorable properties of colloidal nanocomposite were attributed to the stable and well distribution Au NPs on rMGO.