• 文献标题:   Preparation of Shape-Stabilized Phase Change Material by the Valorization of Oil Palm Waste: Reduced Graphene Oxide-activated Carbon Derived Carbon Matrix for Thermal Energy Storage
  • 文献类型:   Article
  • 作  者:   NASIR S, HUSSEIN MZ, ZAINAL Z, YUSOF NA
  • 作者关键词:   porous carbon matrix, nnonadecane, encapsulation, shapestabilized composite, phase change material, latent heat, thermal energy storage
  • 出版物名称:   BIORESOURCES
  • ISSN:   1930-2126
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.15376/biores.16.1.96-117
  • 出版年:   2021

▎ 摘  要

A shape-stabilized composite phase change material (SCPCM) made of n-nonadecane infused by capillary forces in a compressed reduced graphene oxide-activated carbon matrix (EFB(rGOAC)-M) was prepared from oil palm empty fruit bunch. The composite exhibited improved thermal properties and was used to fabricate an SCPCM by impregnation, in which the pores of the EFB(rGOAC)-M served as the support, while n-nonadecane was the central envelope. The EFB(rGOAC)-M exhibited a specific surface area of 680 m(2) g(-1) and an average pore size of 22 angstrom. The successful infiltration of n-nonadecane into the pores of EFB(rGOAC)-M was confirmed via nitrogen gas adsorption-desorption isotherms and scanning electron micrographs. According to the differential scanning calorimeter analysis, the composite SCPCM-5 exhibited melting and freezing temperatures of 37.25 degrees C and 25.58 degrees C, respectively, and an associated latent heat value of 82.72 J g(-1 )and -62.22 J g(-1), respectively. There was no seepage during the phase change process (from solid to liquid, as the n-nonadecane was uniformly dispersed in the pores of the carbon matrix (EFB(rGOAC)-M) and held by the capillary and the surface tension forces of the carbon matrix. This innovative, inexpensive and environmentally friendly shape-stabilized phase change material could be applied for thermal energy storage applications.