• 文献标题:   AuNPs/Neutral red-biofunctionalized graphene nanocomposite for nonenzymatic electrochemical detection of organophosphate via NO2 reduction
  • 文献类型:   Article
  • 作  者:   SINGH M, KASHYAP H, SINGH PK, MAHATA S, RAI VK, RAI A
  • 作者关键词:   biofunctionalization, graphene, gold nanoparticle, bovine serum albumin, methyl parathion, electrochemical
  • 出版物名称:   SENSORS ACTUATORS BCHEMICAL
  • ISSN:   0925-4005
  • 通讯作者地址:   Guru Ghasidas Vishwavidyalaya
  • 被引频次:   5
  • DOI:   10.1016/j.snb.2019.03.131
  • 出版年:   2019

▎ 摘  要

The synthesis of AuNPs/neutral red-bio-functionalized graphene is reported and demonstrated as efficient platform for sensitive detection of hazardous organophosphate pesticide 'Methyl Parathion' via reduction of -NO2 group. It was done by functionalization of graphene oxide with protein 'bovine serum albumin'. Further, it was carbodiimide coupled with non-toxic electroactive 'Neutral red' and followed by its decoration with gold nanoparticles. Nafion was employed here as a dispersion medium. Under optimal conditions, a sensitive detection of methyl parathion was recorded with differential pulse voltammetry through efficient reduction of nitro group at modified glassy carbon electrode in the linear range of 0.02 to 0.153 mu M and 0.153-1.36 mu M with the limit of detection 6 nM.