• 文献标题:   Synthesis of Co2SnO4 hollow cubes encapsulated in graphene as high capacity anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG JJ, LIANG JW, ZHU YC, WEI DH, FAN L, QIAN YT
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   55
  • DOI:   10.1039/c3ta13228e
  • 出版年:   2014

▎ 摘  要

A Co2SnO4 hollow cube/graphene composite (Co2SnO4 HC@rGO) was synthesized by pyrolysis-induced transformation from the hydrothermally synthesized hollow cubic precursor and subsequent combination with graphene sheets via the analogous mechanism of electrostatic interactions. The Co2SnO4 HCs with a size of 240 nm and the shell of 50-70 nm thickness were uniformly encapsulated in the graphene sheets. As an anode material for lithium-ion batteries, the Co2SnO4 HC@rGO exhibited significantly enhanced cyclability and superior rate capability compared to the pure Co2SnO4 counterpart. Even after 100 cycles, it still delivered a capacity over 1000 mA h g(-1) at 100 mA g(-1).