▎ 摘　　要

The extraordinary thermal and elastic properties of graphene, mainly originating from its unique acoustic phonon branches near Gamma point in Brillouin zone, have attracted great attention in its fundamental researches and practical applications. Here, we introduce an optical technique to accurately probe longitudinal acoustic (LA) and transverse acoustic (TA) phonon branches of graphene near Gamma point by double resonant Raman scattering of the combination phonon modes in the range of 1650 - 2150 cm(-1) along with the overtone 2D' mode at similar to 3200 cm(-1). The corresponding sound velocities (nu(TA) = 12:9 km/s,nu(LA) = 19.9 km/s) of graphene have been accessed, which are about 10% smaller than those of graphite. Based on nu(TA) and nu(LA), the two-dimensional (2d) elastic stiffness (tension) coefficients c(11) and c(66), Young's modulus Y-2d and Poisson's ratio sigma(2d) can be estimated. The results demonstrate again that double resonant Raman spectroscopy is a powerful tool to probe the fundamental properties of graphene. (C) 2019 Elsevier Ltd. All rights reserved.