• 文献标题:   Thermochemistry of nitrogen-doped reduced graphene oxides
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   SANDOVAL S, MUTHUSWAMY E, CHEN JW, FUERTES A, TOBIAS G, NAVROTSKY A
  • 作者关键词:   ndoped graphene oxide, calorimetry, stability
  • 出版物名称:   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • ISSN:   0955-2219 EI 1873-619X
  • 通讯作者地址:   Arizona State Univ
  • 被引频次:   1
  • DOI:   10.1016/j.jeurceramsoc.2020.01.043
  • 出版年:   2020

▎ 摘  要

The thermodynamic stability of a series of nitrogen - doped reduced graphene oxides prepared by ammonolysis of graphene oxide has been investigated by high temperature oxidation calorimetry. In terms of enthalpy and depending on the concentration of nitrogen, the nitrogen - doped reduced graphene oxides can be up to 73 kJ.mol(-1) more stable than graphite plus nitrogen. There is a linear relationship between the nitrogen content and the formation enthalpy, which indicates a decrease in stability with increasing nitrogen content.