• 文献标题:   Insight into the Capacitive Performance of Sulfur-Doped Nanoporous Carbons Modified by Addition of Graphene Phase
  • 文献类型:   Article
  • 作  者:   SEREDYCH M, SINGH K, BANDOSZ TJ
  • 作者关键词:   sdoped nanoporous carbon, graphene/carbon composite, capacitance, conductivity, surface chemistry, porosity
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   CUNY City Coll
  • 被引频次:   35
  • DOI:   10.1002/elan.201300161
  • 出版年:   2014

▎ 摘  要

The composites of nanoporous carbon and graphene were prepared by carbonization of mixed sulfonate-based polymers and graphite oxide. Addition of the graphene phase modified the texture and chemistry of the final products. The materials show high electrochemical capacity in spite of the relatively low surface area. The good performance is linked to the presence of sulfur in the small pores, which brings a positive charge on carbon atoms and thus increases the attraction to anions, to the sulfones, sulfoxides and quinones in larger pores, which undergo Faradaic reactions, and to the balanced content of oxygen groups, which provides the wettability.