• 文献标题:   Using carbamide for preparing nitrogen-doped graphene hydrogels to enhance supercapacitor performance
  • 文献类型:   Article
  • 作  者:   SU WF, GAO DM, ZHENG WC, LU F, LIU JY, CHEN XC, SHA O, CHEN L
  • 作者关键词:   nitrogendoped, carbamide, graphene, hydrogel, specific capacitance
  • 出版物名称:   MATERIALS TECHNOLOGY
  • ISSN:   1066-7857 EI 1753-5557
  • 通讯作者地址:   Yanshan Univ
  • 被引频次:   2
  • DOI:   10.1080/10667857.2019.1662982 EA SEP 2019
  • 出版年:   2020

▎ 摘  要

In this paper, nitrogen-doped graphene hydrogel (NGH) has been synthesised by chemically reducing aqueous graphene oxide (GO) solution in the presence of carbamide.Its nitrogen content reaches 8.97 at%. It exhibits a 3D porous network structure with pore sizes of about 2 to 4 mu m comparable to the graphene hydrogel (GH) prepared without nitrogen source. Meanwhile, the NGH shows same hierarchical mesoporous structure with dominant pore size about 2-5 nm as the GH's. Besides, its specific surface area (132.8 m(2) g(-1)) is higher than that of the GH (122.9 m(2) g(-1)). The NGH can deliver an enhanced specific capacitance of 199.80 F g(-1) at 2 A g(-1) compared to that of the GH (142.23 F g(-1)). In addition, the NGH can retain 62.6% of specific capacitance from 2 to 50 A g(-1). The NGH also can maintain 97% of its initial specific capacitance after 20,000 cycles at 10 A g(-1).