• 文献标题:   Graphene oxide and Fe3O4 composite synthesis, characterization and adsorption efficiency evaluation for NO3- and PO43- ions in aqueous medium
  • 文献类型:   Article
  • 作  者:   PERVEEN S, NADEEM R, IQBAL M, BIBI S, GILL R, SAEED R, NOREEN S, AKHTAR K, ANSARI TM, ALFRYYAN N
  • 作者关键词:   graphene oxide, nanocomposite, adsorption, kinetic, inorganic ion
  • 出版物名称:   JOURNAL OF MOLECULAR LIQUIDS
  • ISSN:   0167-7322 EI 1873-3166
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.1016/j.molliq.2021.116746 EA JUL 2021
  • 出版年:   2021

▎ 摘  要

In view of auspicious adsorption efficiency of nanocomposites (NCs), nanocomposites of graphene oxide (GO) were prepared with Fe3O4 by ultrasonic-assisted co-precipitation procedure and characterized by Fourier Transform Infra-red (FTIR), Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and Energy Dispersive X-Ray (EDX). The GO-Fe3O4 NCs were employed for adsorptive elimination of nitrate (NO3-) and phosphate (PO43-) ions from aqueous medium as a function of pH (1-10), GO-Fe3O4 NCs dose (0.05-0.1 g), contact time (0-1444 min) and ions concentration (10-100 mg L-1). Among kinetic and isotherms models, NO3- and PO43- ions removal followed the pseudo second order and Freundlich isotherm models. The maximum elimination capacity was achived up to 89 and 93 (%) for NO3- and PO43- ions, respectively at optimum operating conditions viz. pH 2, ions inital concentration 100 mg L-1, NCs dose 0.5 g and contact time 120 min. For the optimization of process variables, response surface methodology (RSM) was emplyed. The results revealed that GO-Fe3O4 NCs have promising adsorption capacity for NO3- and PO43- ions and can be employed for the removal of NO3- and PO43- ions from effluents. (C) 2021 Elsevier B.V. All rights reserved.