• 文献标题:   Graphene Oxide as a Sulfur Immobilizer in High Performance Lithium/Sulfur Cells
  • 文献类型:   Article
  • 作  者:   JI LW, RAO MM, ZHENG HM, ZHANG L, LI YC, DUAN WH, GUO JH, CAIRNS EJ, ZHANG YG
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • ISSN:   0002-7863
  • 通讯作者地址:   Univ Calif Berkeley
  • 被引频次:   1024
  • DOI:   10.1021/ja206955k
  • 出版年:   2011

▎ 摘  要

The loss of sulfur cathode material as a result of polysulfide dissolution causes significant capacity fading in rechargeable lithium/sulfur cells. Here, we use a chemical approach to immobilize sulfur and lithium polysulfides via the reactive functional groups on graphene oxide. This approach enabled us to obtain a uniform and thin (around tens of nanometers) sulfur coating on graphene oxide sheets by a simple chemical reaction-deposition strategy and a subsequent low-temperature thermal treatment process. Strong interaction between graphene oxide and sulfur or polysulfides enabled us to demonstrate lithium/sulfur cells with a high reversible capacity of 950-1400 mA h g(-1) and stable cycling for more than 50 deep cycles at 0.1C (1C = 1675 mA g(-1)).