• 文献标题:   Physically mixed Ni2Co/graphene catalyst for enhanced glucose oxidation in a glucose fuel cell
  • 文献类型:   Article, Early Access
  • 作  者:   LI Y, DING J, LIU XH, WANG J, JIAO SP, KANG N, LI JY, IRFAN M, ZHANG PP
  • 作者关键词:   direct glucose alkaline fuel cell, reduced graphene oxide, nonnoble metal, anode
  • 出版物名称:   BIOMASS CONVERSION BIOREFINERY
  • ISSN:   2190-6815 EI 2190-6823
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1007/s13399-022-02317-3 EA JAN 2022
  • 出版年:   2022

▎ 摘  要

Glucose oxidation reaction is kinetically sluggish and demands a highly efficient catalyst. Herein, we report a direct glucose alkaline fuel cell (DGAFC) using physically mixed Ni2Co nanoparticles and reduced graphene oxide (Ni2Co-rGO) supported on nickel foam as an anode to promote glucose oxidation. The DGAFC with the Ni2Co-rGO anode delivered a remarkably enhanced peak power density of 40.44 W/m(2) at room temperature, which was 74.91% higher than the control (23.12 W/m(2)). Different techniques including XPS, SEM, linear sweep voltammetry, and electrochemical impedance spectroscopy were used to explore the physiochemical and electrochemical properties of the catalyst. Our results demonstrate that Ni2Co-rGO exhibits an excellent activity toward glucose oxidation in alkaline medium, leading to a drastic improvement in the anode performance. There should be a synergistic effect between rGO and NNi2Co. In the Ni2Co-rGO nanocomposite, rGO not only acts as a support for the Ni2Co nanoparticles and also promotes the electron transfer during the glucose oxidation process. This study can promote the development of bi-transition metal-based catalysts for DGAFCs.