▎ 摘　　要

Herein, we designed graphene oxide (GO)-encapsulated Ag nanoparticle (AgNP)-coated silk fibers with GO serving as the protective film through hyperbranched poly(amide-amine) (HBPAA)-directed self-assembly for protecting AgNP coatings from detachment. Robust, hard, and closely fitted protective films were achieved on the fiber surfaces through self-assembled GOs by introducing 2D GO nanosheets. Silk fibers were hierarchically coated with HBPAA-capped AgNPs (HBPAA/AgNPs) and GOs by successively impregnating the fibers in solutions of HBPAA/AgNPs and GOs to design a well-defined hierarchical structure. In such structure, HBPAA served as a "double-sided tape" not only gluing AgNPs to the fiber surfaces but also adhering GOs to the surfaces of HBPAA/AgNPs. The developed coaxial cable-structured coatings could isolate Ag nanocoatings from external stimuli, opening a potential route to improve the function persistence and biosafety of AgNP-coated biotextiles.