• 文献标题:   Intercalated reduced graphene oxide and its content effect on the supercapacitance performance of the three dimensional flower-like beta-Ni(OH)(2) architecture
  • 文献类型:   Article
  • 作  者:   PARVEEN N, ANSARI SA, ANSARI SG, FOUAD H, CHO MH
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Yeungnam Univ
  • 被引频次:   9
  • DOI:   10.1039/c7nj01915g
  • 出版年:   2017

▎ 摘  要

Anchoring of three dimensional (3D) metal oxides with a controlled morphology on a reduced graphene sheet (rGO) is a promising and challenging route towards the development of highly efficient electrode materials for supercapacitor applications. Herein, we have designed an interconnected 3D flower-like beta-Ni(OH)(2)@rGO (3D-FL-NiH@rGO) architecture and studied the effect of rGO on the morphology as well as supercapacitive performance of 3D-FL-NiH in detail. By varying the experimental parameters, the optimized 3D-FL-NiH@rGO composite achieved the highest capacitance of similar to 1710 F g(-1) at a current load of 2 A g(-1) and also exhibited outstanding cycling performance as compared to the bare 3D-FL-NiH. Further investigation revealed that the improved capacitance of 3D-FL-NiH@rGO is due to the unique 3D and flower like architecture of 3D-FL-NiH which provides a high surface area (124.21 m(2) g(-1)) and more optimal mesoporous size (similar to 8-15 nm) as compared to the corresponding value of 72.9 m(2) g(-1) and microporous size of the bare 3D-FL-NiH. The presence of rGO and 3D-FL of the beta-NiH provided strain relaxation during the charge-discharge procedures, which enhanced the electrical conductivity of the electrode and hence improved the cycling performance of 3D-FL-NiH@rGO.