• 文献标题:   Nitrogen-Doped Graphene and Its Application in Electrochemical Biosensing
  • 文献类型:   Article
  • 作  者:   WANG Y, SHAO YY, MATSON DW, LI JH, LIN YH
  • 作者关键词:   graphene, nitrogen doping, electrocatalysi, direct electrochemistry, biosensing
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   1398
  • DOI:   10.1021/nn100315s
  • 出版年:   2010

▎ 摘  要

Chemical doping with foreign atoms is an effective method to intrinsically modify the properties of host materials. Among them, nitrogen doping plays a critical role in regulating the electronic properties of carbon materials. Recently, graphene, as a true two-dimensional carbon material, has shown fascinating applications in bioelectronics and biosensors. In this paper, we report a facile strategy to prepare N-doped graphene by using nitrogen plasma treatment of graphene synthesized via a chemical method. Meanwhile, a possible schematic diagram has been proposed to detail the structure of N-doped graphene. By controlling the exposure time, the N percentage in host graphene can be regulated, ranging from 0.11 to 1.35%. Moreover, the as-prepared N-doped graphene has displayed high electrocatalytic activity for reduction of hydrogen peroxide and fast direct electron transfer kinetics for glucose oxidase. The N-doped graphene has further been used for glucose biosensing with concentrations as low as 0.01 mM in the presence of interferences.