• 文献标题:   Graphene/Sulfur@Graphene Composite Structure Material for a Lithium-Sulfur Battery Cathode
  • 文献类型:   Article
  • 作  者:   TAO ZR, XIAO JR, YANG ZY, WANG H
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF NANOMATERIALS
  • ISSN:   1687-4110 EI 1687-4129
  • 通讯作者地址:   Guilin Univ Technol
  • 被引频次:   1
  • DOI:   10.1155/2019/6480236
  • 出版年:   2019

▎ 摘  要

Graphene/sulfur@graphene composite structure as a cathode material is synthesized with a facile method. Graphene can provide a more efficient conductive network for sulfur and improve the coulombic efficiency of the battery. On the other hand, it may also show the anchoring effect on sulfur, which reduces the loss of sulfur and improves the cycling performance of the battery. Due to the unique structure, the initial discharge capacity of a battery assembled with this structure could reach 1036mAhg(-1) at 0.1 C, and its reversible capacity of 619mAhg(-1) was retained after 200 cycles with a low fading rate of 0.2% per cycle. The battery could hold a discharge capacity of 501mAhg(-1) after 200 cycles at 0.5 C. Thus, the electrochemical performance improved because of the reduction of sulfur loss through polysulfide accumulation at the cathode.