• 文献标题:   Graphene from Alginate Pyrolysis as a Metal-Free Catalyst for Hydrogenation of Nitro Compounds
  • 文献类型:   Article
  • 作  者:   TRANDAFIR MM, FLOREA M, NEATU F, PRIMO A, PARVULESCU VI, GARCIA H
  • 作者关键词:   alginate, carbocatalysi, graphene, hydrogenation, metalfree catalyst
  • 出版物名称:   CHEMSUSCHEM
  • ISSN:   1864-5631 EI 1864-564X
  • 通讯作者地址:   Univ Politecn Valencia
  • 被引频次:   21
  • DOI:   10.1002/cssc.201600197
  • 出版年:   2016

▎ 摘  要

Graphene obtained by pyrolysis of alginate at 900 degrees C under inert atmosphere and exfoliation is used as a metal-free catalyst for reduction of nitro to amino groups with hydrogen as a reagent. The process is general for aromatic and aliphatic, conjugated and isolated nitro groups, and occurs with low selectivity over hydrogenation of carbon-carbon double bonds.