• 文献标题:   Graphene Oxide-Dispersed Pristine CNTs Support for MnO2 Nanorods as High Performance Supercapacitor Electrodes
  • 文献类型:   Article
  • 作  者:   YOU B, LI N, ZHU HY, ZHU XL, YANG J
  • 作者关键词:   electrochemistry, energy storage, graphene, nanotube, supercapacitor
  • 出版物名称:   CHEMSUSCHEM
  • ISSN:   1864-5631
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   60
  • DOI:   10.1002/cssc.201200709
  • 出版年:   2013

▎ 摘  要

A MnO2CNTgraphene oxide (MCGO) nanocomposite is fabricated using graphene oxide (GO) as a surfactant to directly disperse pristine carbon nanotubes (CNTs) for the subsequent deposition of MnO2 nanorods. The resulting MCGO nanocomposite is used as a supercapacitor electrode that shows ideal capacitive behavior (i.e., rectangular-shaped cyclic voltammograms), large specific capacitance (4.7times higher than that of free MnO2) even at high mass loading (3.0mgcm2), high energy density (30.414.2Whkg1), large power density (2.650.5kWkg1), and still retains approximately 94% of the initial specific capacitance after 1000cycles. The advanced capacity, rate capability, and cycling stability may be attributed to the unique architecture, excellent ion wettability of GO with enriched oxygen-containing functional groups, high conductivity of CNTs, and their synergistic effects when combined with the other components. The results suggest that the MnO2CNTGO hybrid nanocomposite architecture is very promising for next generation high-performance energy storage devices.