• 文献标题:   Characterization of Low Temperature Graphene Synthesis in Inductively Coupled Plasma Chemical Vapor Deposition Process with Optical Emission Spectroscopy
  • 文献类型:   Article
  • 作  者:   MA Y, KIM D, JANG H, CHO SM, CHAE H
  • 作者关键词:   graphene, plasma enhanced chemical vapor deposition pecvd
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Sungkyunkwan Univ SKKU
  • 被引频次:   7
  • DOI:   10.1166/jnn.2014.10098
  • 出版年:   2014

▎ 摘  要

Low-temperature graphene was synthesized at 400 degrees C with inductively coupled plasma chemical vapor deposition (PECVD) process. The effects of plasma power and flow rate of various carbon containing precursors and hydrogen on graphene properties were investigated with optical emission spectroscopy (OES). Various radicals monitored by OES were correlated with graphene film properties such as sheet resistance, I-D/I-G ratio of Raman spectra and transparency. C2H2 was used as a main precursor and the increase of plasma power enhanced intensity of carbon (C-2) radical OES intensity in plasma, reduced sheet resistance and increased transparency of graphene films. The reduced flow rate of C2H2 decreased sheet resistance and increased transparency of graphene films in the range of this study. H-2 addition was found to increase sheet resistance, transparency and attributed to reduction of graphene grain and etching graphene layers. OES analysis showed that C-2 radicals contribute to graphite networking and sheet resistance reduction. TEM and AFM were applied to provide credible information that graphene had been successfully grown at low temperature.