• 文献标题:   Selective sensing and mechanism of patterned graphene-based sensors: Experiments and DFT calculations
  • 文献类型:   Article
  • 作  者:   YE XH, QI M, YANG HY, MEDIKO FS, QIANG H, YANG YL, HE CZ
  • 作者关键词:   selective sensing, patterned graphene, femtosecond laser, dft calculation, sensing mechanism
  • 出版物名称:   CHEMICAL ENGINEERING SCIENCE
  • ISSN:   0009-2509 EI 1873-4405
  • 通讯作者地址:  
  • 被引频次:   11
  • DOI:   10.1016/j.ces.2021.117017 EA AUG 2021
  • 出版年:   2022

▎ 摘  要

Graphene with antidots shows great potential in wearable devices and highly sensitive sensors. In this paper, we fabricated the patterned graphenes of circle, square, and triangle by ultrafast laser processing. The given patterned graphene can precisely detect one specific gas from the CO/NO/H2O-mixed gases. The sensing performance results demonstrated that the circle patterned graphene (cir-graphene) was most sensitive to CO with the highest sensitivity with the gauge factor (GF) of 3.9 x 10(4). For NO sensing, the triangle patterned graphene (tri-graphene) conducted the best results. The square patterned graphene (squ-graphene) was the most sensitive to H2O. The DFT calculations revealed that CO was chemical adsorbed on cir-graphene with the most negative adsorption energy (-3.638 eV). For NO sensing, tri-graphene performed best. While, the patterned graphene was not available to H2O sensing. This work offers a novel solution to next-generation wearable multifunctional sensors, and a new insight for the selective sensing mechanism. (C) 2021 Elsevier Ltd. All rights reserved.