• 文献标题:   Graphene-based in-plane micro-supercapacitors with high power and energy densities
  • 文献类型:   Article
  • 作  者:   WU ZS, PARVEZ K, FENG XL, MULLEN K
  • 作者关键词:  
  • 出版物名称:   NATURE COMMUNICATIONS
  • ISSN:   2041-1723
  • 通讯作者地址:   Max Planck Inst Polymer Res
  • 被引频次:   710
  • DOI:   10.1038/ncomms3487
  • 出版年:   2013

▎ 摘  要

Micro-supercapacitors are important on-chip micro-power sources for miniaturized electronic devices. Although the performance of micro-supercapacitors has been significantly advanced by fabricating nanostructured materials, developing thin-film manufacture technologies and device architectures, their power or energy densities remain far from those of electrolytic capacitors or lithium thin-film batteries. Here we demonstrate graphene-based in-plane interdigital micro-supercapacitors on arbitrary substrates. The resulting micro-supercapacitors deliver an area capacitance of 80.7 mu Fcm(-2) and a stack capacitance of 17.9 F cm(-3). Further, they show a power density of 495Wcm(-3) that is higher than electrolytic capacitors, and an energy density of 2.5mWhcm(-3) that is comparable to lithium thin-film batteries, in association with superior cycling stability. Such microdevices allow for operations at ultrahigh rate up to 1,000Vs(-1), three orders of magnitude higher than that of conventional supercapacitors. Micro-supercapacitors with an in-plane geometry have great promise for numerous miniaturized or flexible electronic applications.